Facile synthesis of palladium nanoparticles supported on multi-walled carbon nanotube for efficient hydrogenation of biomass-derived levulinic acid

摘要

Different loading of palladium (Pd) nanoparticles were successfully fabricated on multi-walled carbon nanotubes using Pd acetylacetonate as the precursor via a simple liquid impregnation method. The crystal phase, morphology, textural structure and the chemical state of the resulting Pd nanoparticles (Pd/CNT) catalysts were studied and the characterization results indicated that the uniform dispersion of small Pd nanoparticles with the size range of 1.0-4.5 nm was achieved. The synthesized Pd/CNT catalysts exhibited efficient performance for the catalytic hydrogenation of biomass-derived levulinic acid into biofuel γ-valerolactone. In comparison with the commercial 5 wt Pd/C and the 5 wt Pd/CNT catalyst prepared by Pd nitrate precursor, much higher activities were achieved, whereas the biofuel γ-valerolactone was highly produced with 56.3 yield at 57.6 conversion of levulinic acid on the 5 wt Pd/CNT catalyst under mild conditions. The catalyst developed in this work may be a good candidate for the wide applications in the hydrogenation.