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Physical properties of disordered double-perovskite Ca_(2-x)La_(x)FelrO_(6)

机译:无序双钙钛矿Ca_(2-x)La_(x)FelrO_(6)的物理性质

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摘要

In this work we have synthesized polycrystalline samples for the series of double-perovskite Ca_(2-x)La_(x)FeIrO_(6). Their structural and magnetic properties were investigated using experiments of magnetic susceptibility and x-ray powder diffraction. The Ca_(2-x)La_(x)FeIrO_(6) compounds form in a monoclinic structure, space group P21/n, with the presence of significant Fe/Ir cationic disorder. Interestingly, our results indicate a change in the nature of the microscopic magnetic interaction induced by La doping, where the system seems to evolve from antiferromagnetic in the extremities of the series, x(velence)0 (T_(N) approx= 75 K) and x(velence)2.0, to ferrimagnetic in intermediate regions of the series. However, due to significant presence of disorder and strong competition between ferromagnetic and antiferromagnetic interactions, the saturation of the magnetization was not found to be larger than 0.1(mu)_(B)/Fe.
机译:在这项工作中,我们合成了双钙钛矿系列的多晶样品 Ca_(2-x)La_(x)FeIrO_(6)。通过磁化率和X射线粉末衍射实验研究了它们的结构和磁性能。Ca_(2-x)La_(x)FeIrO_(6) 化合物形成单斜晶系结构,空间群 P21/n,存在明显的 Fe/Ir 阳离子紊乱。有趣的是,我们的结果表明,由La掺杂引起的微观磁相互作用的性质发生了变化,其中系统似乎从系列x(velence)0(T_(N)approx= 75 K)和x(velence)2.0的反铁磁性演化到系列中间区域的亚铁磁性。然而,由于铁磁和反铁磁相互作用之间存在显著的无序和强烈竞争,磁化强度的饱和度未大于0.1(μ)_(B)/Fe。

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