Five and six coordinate complexes of triorganotin (IV) moieties with Schiff bases derived from S-methyl or -benzyldithiocarbazate and a ketone or pyridine-2-carboxaldehyde, respectively, have been synthesised and characterized by elemental analysis, molar conductance, molecular weight determination and ultraviolet and infrared spectroscopy. The complexes are nonelectrolytic and monomeric in solution.
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