Mathematical methods are presented for calculating rate constants of processes which narrow nuclear magnetic resonance absorption lines having discrete components. High resolution proton spectra show that the R1COhyphen;NR2R3skeletons of N,Nhyphen;dimethylformamide (DMF) and N,Nhyphen;dimethylacetamide (DMA) are planar and suggest that Nhyphen;methylformamide, Nhyphen;methylacetamide, Nhyphen;methylformanilide and Nhyphen;methylacetanilide exist predominantly in one configuration. The presence of a significant amount of double bond character in the Csngbnd;N amide bond is proved by the temperature dependent coalescence observed for the chemically shifted proton doublet of the N(CH3)2groups in DMF and DMA, which gives values of about 22 and 19 kcal respectively for the free energy of activation required for reorientations about the bond.
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