Two-photon absorption property of Cl-substituted diphenylacetylenes by optical-probing photoacoustic spectroscopy

摘要

abstract_textpTwo-photon absorption spectra and two-photon absorption cross sections of Cl-substituted diphenylacetylenes (ClDPAs) were investigated by optical-probing photoacoustic spectroscopy and quantum chemical calculations for the first time. The two-photon absorption spectra of ClDPAs exhibited intense two-photon absorption bands at around 480 nm, which are forbidden by one-photon absorption. The two-photon absorption cross sections sigma((2)) of o-, m-, and p-ClDPAs at 476 nm were determined to be 22 +/- 1, 23 +/- 1, and 38 +/- 2 GM, respectively. Compared with diphenylacetylene (DPA) (27 GM at 472 nm), the sigma((2)) values of o- and m-ClDPAs were lower, while that of p-ClDPA was higher. Simulated two-photon absorption spectra using the TD-B3LYP/6-311+G(d,p) level of calculations within the Tamm-Dancoff approximation, based on the three-state model, well agreed with the experimental results. The difference in the sigma((2)) values of DPA and ClDPAs was responsible for those in the transition dipole moments between the intermediate and the final states./p/abstract_text