Application of the Ewald method to the evaluation of the Madelung potential of a crystal slab possessing twohyphen;dimensional periodicity has been studied. The method involves a simple differential equation to be solved. When each crystallographic plane parallel to the surface contains equal amounts of opposite charges, the unique boundary condition leads to a unique solution and the correct Madelung potential in the surface region and the bulk. If the planes are not charge neutral, the boundary condition is ambiguous. A slab consisting of a dipoleless repeating unit layer satisfies a unique boundary condition. The method is applied to NaCl, CsCl, and bgr;hyphen;alumina. A simple surface modification is shown to produce the slab bulk selfhyphen;potential equal to the infinite crystal bulk selfhyphen;potential.
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