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The effect of radiation on the OH−infrared absorption of quartz crystals

机译:辐射对石英晶体OH红外吸收的影响

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The effect of 1.6‐MeV‐electron irradiation on the infrared properties of high‐purity quartz crystals has been studied. The infrared bands assciated with OH−impurities in SiO2crystals are strongly temperature dependent and must be studied at 77 K or below. Prolonged electron irradiation at low temperature suppresses all of the OH−bands, but these bands recover when the crystals are annealed to approximately 740 K. If as‐grown crystals are irradiated at 300 K, the intensity of the OH−bands decreases and two new bands appear at 3367 and 3306 cm−1. The relative absorption intensity of these two bands depends on radiation temperature and dose.
机译:研究了1.6‐MeV‐电子辐照对高纯度石英晶体红外性能的影响.SiO2晶体中与OH杂质结合的红外带具有很强的温度依赖性,必须在77 K或更低的温度下进行研究。在低温下长时间的电子辐照会抑制所有的OH带,但是当晶体退火到大约740 K时,这些能带会恢复。如果在300 K下照射生长晶体,OH带的强度降低,并在3367和3306 cm-1处出现两个新的带。这两个波段的相对吸收强度取决于辐射温度和剂量。

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