Analytic solution of the molecular Ornsteinndash;Zernike equation for nonspherical molecules. Spheres with anisotropic surface adhesion

摘要

The molecular Ornsteinndash;Zernike equation is solved for a fluid of hard spheres with anisotropic surface adhesion yielding a small set of nonlinear algebraic equations which must be solved numerically in order to obtain structural and thermodynamic properties. It is argued that such a model may mimic the shorthyphen;ranged, anistropic interactions encountered in hydrogenhyphen;bonded fluids such as water.