Quenching and rotational coupling rate coefficients have been measured for theJ=4ndash;10,v=0 levels of thealsquo;thinsp;1Sgr;g+metastable state of N2in collisions with ground state N2. Laser absorption is used to monitor the population of rotational levels of thealsquo;thinsp;1Sgr;g+state following depletion of the population of one or more levels by optical pumping to other states. The observed time dependence of the recovery of population of the perturbed level and the collision induced growth and decay of the populations of adjacent levels are interpreted in terms of quenching to other electronic levels and excitation exchange among adjacent rotational levels. For theJ=6,v=0 level of thealsquo;thinsp;1Sgr;g+state the rate coefficients extrapolated to zero discharge current at 300 K are 2.3plusmn;0.1times;10minus;16m3/s for electronic quenching and 1.1plusmn;0.6times;10minus;16m3/s for excitation transfer to theJ=4 andJ=8 levels in collisions with N2. Very similar rate coefficients were obtained for theJ=4, 7, and 8 levels.
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