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Urea impregnation to enhance porosity development of carbons prepared from phenol-formaldehyde resins

机译:尿素浸渍增强酚醛树脂制备的碳的孔隙率

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摘要

Because of the considerably high fixed carbon content and the characteristic random configuration of the resulting carbon 1, phenol-formaldehyde resins have become increasingly important as precursors for porous carbons in the form of fibers or particles 2,3. It has been reported in our previous studies that high porosity carbons can be produced from the resins using either physical or chemical activation methods 3,4. Physical activation is preferred for mass production in industry because of environmental and economical concerns. However, the yield of the high porosity carbons from physical activation is usually low, due to the fact that the development of pores in the carbons is achieved by eliminating a large amount of internal carbon mass. Apart from the effect of activation degree, it is generally recognized that the porosity of the carbon from physical activation is dictated by the type of precursor used as well as the structure of resulting chars from carbonization 5.
机译:由于相当高的固定碳含量和所得碳的特征随机构型[1],酚醛树脂作为纤维或颗粒形式的多孔碳的前体变得越来越重要[2,3]。我们之前的研究报道,使用物理或化学活化方法可以从树脂中产生高孔隙率碳[3,4]。由于环境和经济方面的考虑,物理活化是工业大规模生产的首选。然而,由于碳中孔隙的发展是通过消除大量的内部碳质量来实现的,因此物理活化产生的高孔隙率碳的产率通常较低。除了活化程度的影响外,人们普遍认为,物理活化产生的碳的孔隙率取决于所用前驱体的类型以及碳化产生的炭的结构[5]。

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