首页>
外文期刊>journal of chemical physics
>Raman Phonon Spectra of Isotopic Mixed Naphthalene Crystals: Librational Exciton Model and the Amalgamation Limit
【24h】
Raman Phonon Spectra of Isotopic Mixed Naphthalene Crystals: Librational Exciton Model and the Amalgamation Limit
展开▼
机译:Raman Phonon Spectra of Isotopic Mixed Naphthalene Crystals: Librational Exciton Model and the Amalgamation Limit
We present an experimental Raman study of lattice modes in neat and mixed (10percnt;ndash;90percnt;) crystals of naphthalenehyphen;h8and naphthalenehyphen;d8at 100deg;K with 1 cmminus;1resolution. The spectral features of the neat crystals are preserved in the heavily doped mixed crystals, with small shifts and broadenings characteristic of an amalgamation limit that assumes weakly coupled excitation bands in the restricted Frenkelhyphen;Davydov limit. Rotationhyphen;translation interaction does not affect the mixed crystal spectra, thus making the Raman technique uniquely suited for the investigation of the librational (rotational) phonon band structure. The evidence is against localized or pseudolocalized phonons in these isotopic mixed crystals.
展开▼