Photopolymerization of methyl methacrylate using benzoin isopropyl ether as photoinitiator: Effect of thiophenol compounds

摘要

AbstractEffects of a series of thiophenolsRArSH with substituting groupsRin thepara‐position and 2‐mercaptobenzoic acid on the kinetics of polymerization of methyl methacrylate (MMA) photoinitiated by benzoin isopropyl ether (BIPE) were investigated using an autorecording dilatometer. Thiophenols were found to have a dual effect on polymerization: reducing induction time and accelerating rate of polymerization. A mechanism was proposed suggesting that this increased rate of polymerization and reduced induction time with addition of a thiophenol is due to the fact that, instead of consuming radicals, the dissolved oxygen in the MMA/BIPE system can be converted into active radicals through effective photooxidation of the thiophenol. Although the maximum increase in rate of polymerization is of a minor difference between various thiophenol compounds, reduction in induction time is strongly dependent on the nature of substituting groups in the following order: CH3>CH(CH3)2>OCH3or Cl>H. 2‐Mercaptobenzoic acid, on the other hand, increases induction time and decreases rate of polymerization. © 1993 Jo