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Shear flow rheological properties, fiber damage, and mastication characteristics of aramid‐, glass‐, and cellulose‐fiber‐reinforced polystyrene melts

机译:芳纶、玻璃和纤维素纤维增强聚苯乙烯熔体的剪切流动流变特性、纤维损伤和咀嚼特性

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AbstractAn experimental study of the viscosity and principal normal stress difference of a polystyrene melt filled with aramid (Kevlar), glass, and cellulose fibers is reported. The influence of loading level and mastication on the rheological properties is discussed. The effects of mixing and mastication on fiber damage are considered. Glass fibers break down rapidly to very small aspect ratios, while aramid shows a “kinked” structure, with kinks occurring every 100 μm. A mechanism is proposed for fiber breakage based on buckling during rotation in shear flow. It is found that addition of fibers increases the viscosity in the same manner as a reduction in temperature, and data may be superposed by reduced plotting. This indicates that the viscosity increase is due solely to enhanced viscous dissipation in the matrix and not to interparticle forces as is the case with smaller particles. The principal normal stress difference increases at fixed shear stress with fiber loading. The extent of increase depends upon fiber loading, aspect ratio, and mod
机译:摘要报道了填充芳纶(Kevlar)、玻璃和纤维素纤维的聚苯乙烯熔体的粘度和主法向应力差的实验研究。讨论了负载水平和咀嚼对流变性能的影响。考虑了混合和咀嚼对纤维损伤的影响。玻璃纤维迅速分解到非常小的纵横比,而芳纶则表现出“扭结”结构,每 100 μm 发生一次扭结。提出了一种基于剪切流旋转过程中屈曲的纤维断裂机理。研究发现,纤维的添加与温度降低相同的方式增加粘度,并且数据可以通过减少绘图来叠加。这表明粘度的增加完全是由于基体中粘性耗散的增强,而不是像较小颗粒那样的颗粒间力。主法向应力差在固定剪切应力下随纤维载荷而增大。增加的程度取决于光纤负载、纵横比和模组

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