Der Einfluß großer Salzkonzentrationen auf die Oxydationsreaktion von Fe(phen)32+mit Ce(IV) in Schwefelsäure

摘要

The influence of NaClO4, NaCl and Na2SO4on the oxidation of Fe(phen)32+by Ce(IV) was investigated by means of the stopped-flow method. At the concentrations range of NaClO4and NaCl 0.1–1.0Mthe rate constant values decrease from 1.03·105to 0.56·105M−1s−1and from 1.08·105to 0.81·105M−1s−