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Dynamic mechanical properties of deformed rubber‐modified acrylics

机译:变形橡胶改性丙烯酸树脂的动态力学性能

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AbstractRubber‐modified acrylic polymers with rubber contents of 0, 1, 4, 7, 10, 13, and 16 were investigated to determine the effects of cold deformations on their mechanical and dynamic mechanical properties. A Rheovibron was used to determine damping as a function of temperature at four frequencies. A cold‐rolled film and a cold‐drawn film, stretched until fully crazed, were investigated. It was shown that cold deformation produces a small shift in the glass transition temperature of the rubber phase while the activation energy remains nearly unchanged. Also, the nature of the damping curve of the glassy matrix near the glass transition temperature of the matrix is altered by the appearance of a shoulder in the
机译:摘要研究了橡胶含量为0%、1%、4%、7%、10%、13%和16%的橡胶改性丙烯酸聚合物,以确定冷变形对其力学和动力力学性能的影响。使用流变玻璃来确定阻尼与四个频率下温度的函数关系。研究了冷轧薄膜和冷拔薄膜,拉伸至完全发芽。结果表明,冷变形使橡胶相的玻璃化转变温度发生微小变化,而活化能几乎保持不变。此外,玻璃基体在基体的玻璃化转变温度附近的阻尼曲线的性质会因

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