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ISSN 0300-922X JCPRB4(9) 1081-1 190(1992) JOURNAL OF THE CHEMICAL SOCIETY Perkin Transactions I Organic and Bio-organic Chemistry CONTENTS Perkin Communications 1081 Highly regioselective 2 + 21 photocycloaddition of aromatic aldehydes to acetylfurans Howard A. J. Carless and A. Frank E. Halfhide 1083 Effect of coenzyme analogues on enantioselectivity of alcohol dehydrogenase Changsheng Zheng and Robert S. Philips 1085 A simple strategy for obtaining both enantiomers from an aldolase reaction: preparation of L-and ~-4-hydroxy-2- ketoglutarate Nicholas C. Floyd, Mark H. Liebster and Nicholas J. Turner Articles 1089 N-Alkenyl nitrone dipolar cycloaddition routes to piperidines and indolizidines. Part 3. Approach to the gephyrotoxin ring system Andrew B.Holmes, Andrew B. Hughes, Adrian L. Smith and Simon F. Williams 1101 Preparation and 2 + 31 cycloaddition of thienyl isocyanates with trimethylsilyl azide: one-pot synthesis of thienyl- tetrazolin-5-ones Maurizio Toselli and Paolo Zanirato t1105 Synthesis, separation and absolute configuration assignment to enantiomers of 1,3-benzodithiole 1 -oxide and 2-alkyl- 1,3- benzodithiole 1-oxides Derek R. Boyd, Narain D. Sharma, James H. Dorman, Robert Dunlop, John F. Malone, R. Austin S. McMordie and Alex F. Drake 1111 Mannich/Friedel-Crafts preparations of 1-(arylmethy1)benzotriazoles and synthetic transformations of their lithio derivatives Alan R.Katritzky, Mikhail F. Gordeev, John V. Greenhill and Peter J. Steel 1119 General synthesis of homochiral trisubstituted y-butyrolactones David Alker, D.Neville Jones, G. Mark Taylor and William W. Wood 1127 Cathodic carbonylation of 1 -halogenopentanes Kunihisa Yoshida, Masaru Kobayashi and Sei-ichi Amano 1131 Synthesis and absolute configuration of the naturally occurring cyano glucoside simmondsin Noritaka Chida, Ken Yamada and Seiichiro Ogawa 1139 Heterocyclic transformations. Part 4. A facile transformation of 3-alkyl-6-methyl- 1,3-0xazine-2,4(3H)-diones to 6- substituted 5-acetyluracils and 6-thioxo-l,3,5-triazine-2,4(1 H,3H,SH)-diones Harjit Singh, Pawan Aggarwal and Subodh Kumar 1145 Intramolecular photocycloaddition of 4-phenoxybut- 1-enes: a convenient access to the 4-oxatricyclo7.2.0.03~rsquo;undeca-2,lO-diene skeleton Siham Y.Al-Qaradawi, Kevin B.Cosstick and Andrew Gilbert 1149 Structure and stereochemistry of three phytotoxins, syringomycin, syringotoxin and syringostatin, produced by Pseudornonas syringae pv. syringae Naoyuka Fukuchi, Akira Isogai, Jiro Nakayama, Seiji Takayama, Shuichi Yamashita, Kazuo Suyama, Jon Y. Takemoto and Akinori Suzuki 1159 A chemoenzymatic synthesis of enantiomerically pure (R)-and (S)-2-methyldecan- 1-01 Patrizia Ferraboschi, Paride Grisenti, Ada Manzocchi and Enzo Santaniello 1163 Multiple-column solid-phase glycopeptide synthesis Stefan Peters, Tim Bielfeldt, Morten Meldal, Klaus Bock and Hans Paulsen CONTENTS 1 173 Synthesis of C-functionalized trans-cyclohexyldiethylenetriaminepenta-aceticacids for labelling of monoclonal antibodies with the bismuth-212 a-particle emitter Martin W.Brechbiel and Otto A. Gansow 1179 Reaction and spectra of Cn.2. I( 1,2,3)cyclophanes Akihiko Tsuge, Hironobu Nago, Shuntaro Mataka and Masashi Tashiro 1 187 Conference Diary AUTHOR INDEX Aggarwal, Pawan, 1139 Alker, David, 11 19 Al-Qaradawi, Siham Y.,1145 Amano, Sei-ichi, 1127 Bielfeldt, Tim, 1163 Bock, Klaus, 1163 Boyd, Derek R., 1105 Brechbiel, Martin W., 1173 Carless, Howard A. J., 1081 Chida, Noritaka, 1131 Cosstick, Kevin B., 1145 Dorman, James H., 1105 Drake, Alex F., 1105 Dunlop, Robert, 1105 Ferraboschi, Patrizia, 1159 Floyd, Nicholas C., 1085 Fukuchi, Naoyuka, 1149 Gansow, Otto A., 1173 Gilbert, Andrew, 1145 Gordeev, Mikhail F., 11 11 Greenhill, John V., 1111 Grisenti, Paride, 1 159 Halfhide, A.Frank E., 1081 Holmes, Andrew B., 1089 Hughes, Andrew B., 1089 Isogai, Akira, 1149 Jones, D. Neville, 1 1 19 Katritzky, Alan R., 11 11 Kobayashi, Masaru, 1127 Kumar, Subodh, 1139 Liebster, Mark H., 1085 Malone, John F., 1105 Manzocchi, Ada, 1159 Mataka, Shuntaro, 1179 McMordie, R. Austin S., 1105 Meldal, Morten, 1 163 Nago, Hironobu, 1179 Nakayama, Jiro, 1149 Ogawa, Seiichiro, 1 13 1 Paulsen, Hans, 1163 Peters, Stefan, 1163 Philips, Robert S., 1083 Santaniello, Enzo, 1159 Sharma, Narain D., 1105 Singh, Harjit, 1139 Smith, Adrian L., 1089 Steel, Peter J., 1 11 1 Suyama, Kazuo, 1149 Suzuki, Akinori, 1149 Takayama, Seiji, 1149 Takemoto, Jon Y.,1149 Tashiro, Masashi, 1 179 Taylor, G. Mark, 11 19 Toselli, Maurizio, 1101 Tsuge, Akihiko, 1179 Turner, Nicholas J., 1085 Williams, Simon F., 1089 Wood, William W., 1119 Yamada, Ken, 113 1 Yamashita, Shuichi, 1149 Yoshida, Kunihisa, 1127 Zanirato, Paolo, 1101 Zheng, Changsheng, 1083 NOTE: An asterisk in the heading of each paper indicates the author who is to receive any correspondence. 111

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