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Effects of P_2O_5 and sintering temperature on microstructure and mechanical properties of lithium disilicate glass-ceramics

机译:P_2O_5和烧结温度对二硅酸锂微晶玻璃组织和力学性能的影响

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摘要

This paper investigates the effect of P_2O_5 content and sintering temperature on the microstructure of lithium disilicate glass-ceramics and analyzes the relation between microstructure and mechanical properties. Specimens were prepared by hot-pressing technology, adding 1.0-4.0 mol percent P_2O_5 (G1P, G2P, G3P and G4P). Lithium disilicate (Li_2Si_2O_5), lithium metasilicate (Li_2SiO_3) and lithium orthophos-phate (Li_3PO_4) crystalline phases were detected. The morphology of Li_2Si_2O_5 crystals transformed from rod-shaped to needle-like and the mechanical properties inevitably decreased. Additionally, G1P and G2P were prepared by hot-pressing technology with sintering temperatures ranging 780-840 deg C. The results showed that sintering temperature had no significant effect on the crystalline phases and microstructure. The optimal mechanical performances (flexural strength 290 MPa; fracture toughness 3.3 MPa m~(1/2)) were obtained with 1 mol percent P_2O_5 and a sintering temperature of 820 deg C.
机译:本文研究了P_2O_5含量和烧结温度对二硅酸锂微晶玻璃微观结构的影响,分析了微观结构与力学性能的关系。通过热压技术制备试样,加入1.0-4.0 mol%的P_2O_5(G1P、G2P、G3P和G4P)。检测了二硅酸锂(Li_2Si_2O_5)、偏硅酸锂(Li_2SiO_3)和正磷酸锂(Li_3PO_4)结晶相。Li_2Si_2O_5晶体的形貌由棒状转变为针状,力学性能不可避免地下降。此外,G1P和G2P采用热压技术制备,烧结温度为780-840°C。结果表明,烧结温度对晶相和微观结构无显著影响。在1 mol%P_2O_5和820 °C烧结温度下,获得了最佳的力学性能(弯曲强度290 MPa;断裂韧性3.3 MPa m~(1/2))。

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