Asphalts are widely used in paving of roads, and water-proof sealing of building roofs, tanks and containers. This study evaluated the qualitative and quantitative characteristics of emissions from hot asphalts and bitumen that included reactive organic gases (ROGs) and particulate matter (PM). The ROGs consisted of several volatile organic compounds (VOCs), and semi-volatile organic compounds (SVOCs) of environmental concern. The latter included several polynuclear aromatic hydrocarbons (PAHs) and alkanes. An experimental laboratory testing, sampling and analysis protocol was developed for obtaining efficient and cost-effectivea prioriestimates of asphalt emissions. The investigation identified and quantified the emissions of organics and evaluated the magnitudes as well as particle size distributions of PM emissions. The study demonstrated that the asphalt type and temperature greatly affected the emission characteristics, and that several organic compounds emitted were partitioned between gaseous and particulate phases. The factors that affected the phase distribution of organic compounds included the following: vapor pressures, ambient temperatures, collection methods, stability and reactivity, and affinity for sorption on PM.
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