Selective crosslinking in polymer blends. II. Its effect on impact strength and other mechanical properties of polypropylene/unsaturated elastomer blends

摘要

AbstractThe effect of selective crosslinking of the unsaturated elastomer particles in polypropylene (PP) matrix was investigated. The crosslink system comprisedN,N′‐m‐phenylene‐bismaleimide and 6‐ethoxy‐2,2,4‐trimethyl‐1,2‐dihydroqinoline or polymerized‐(2,2,4‐trimethyl‐1,2‐dihydroquinoline). The system, which produces only carbon radicals, crosslinks the elastomer particles selectively without causing excessive degradation of the PP matrix. The reaction was carried out under a dynamic crosslinking process using a twin extruder on PP/EPDM, PP/SBS, and PP/SIS blends, all of which comprised 80 wt of PP and 20 wt of the elastomer. After the crosslinking, the impact strength of the blends increased. Especially remarkable increase is obtained at 23°C where PP is above itsTg. The increase of interfacial adhesion caused by production of PP/elastomer graft copolymer at the interface is considered to be the most important factor in the improvement. It permits the interactions of the stress concentrate zone developed at the elastomer particles and causes shear yielding of the PP matrix. Impact fracture energy absorption can be thus changed by adjusting the degree of the interfacial adhesion even at essentially the same morphology. The crosslinked elastomer particles also play the role of a nucleation agent. The selective cross‐linking of the elastomer particles in PP/elastomer blends is demonstrated to be an excellent technique to produce a high‐impact, high‐modulus