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Precipitation evolution in Al-Zr and Al-Zr-Ti alloys during isothermal aging at 375-425 deg C

机译:Al-Zr和Al-Zr-Ti合金在375-425°C等温时效过程中的析出演化

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摘要

Formation of Al_3Zr or Al_3(Zr_(1-x) Ti_x) precipitates with a metastable L1_2 structure was investigated in conventionally solidified Al-0.1 Zr, Al-0.2 Zr, Al-0.1 Zr-0.1 Ti, and Al-0.2 Zr-0.2 Ti (at. percent) alloys aged isothermally at 375, 400, or 425 deg C. Pronounced hardening results from nanometer-scale, spheroidal Al_3Zr or Al_3Zr_(1-x)Ti_x (L1_2) precipitates within solute-enriched dendrites. Interdendritic regions contain a significantly lower number density of coarser cauliflower-, rod- and plate-shaped precipitates with the L1_2 structure. Neither the magnitude of the peak-aged hardness, nor the subsequent loss in hardness due to overaging, is affected by ternary additions of Ti. After extended aging times (1600 h) at 425 deg C, there is no difference in the mean precipitate radii of spheroidal Al_3Zr or Al_3(Zr_(1-x)Ti_x) precipitates, confirming that Ti additions do not improve the coarsening resistance. Comparison with prior coarsening studies on Al_3Zr, and Al_3(Zr_(1-x)V_x), Al_3(Zr_(1-x)Ti_x) and Al_3(Zr_(1-x-y)V_xTi_y) (L1_2) precipitates at 425 deg C confirms the lack of an effect from ternary alloying additions.
机译:在375、400或425°C等温时效的常规固化Al-0.1 Zr、Al-0.2 Zr、Al-0.1 Zr-0.1 Ti和Al-0.2 Zr-0.2 Ti(at.%)合金中,研究了具有亚稳态L1_2结构的Al_3Zr或Al_3(Zr_(1-x)L1_2 Ti_x Ti_x)析出物的Al_3Zr_Al_3Zr形成。树枝间区域含有具有L1_2结构的较粗的花椰菜、棒状和板状沉淀物的数量密度明显较低。无论是峰值时效硬度的大小,还是由于过度时效而导致的硬度损失,都不受三元添加Ti的影响。在425°C下延长老化时间(1600 h)后,球状Al_3Zr或Al_3(Zr_(1-x)Ti_x))析出物的平均析出半径没有差异,证实了Ti的添加不会提高抗粗化性。与先前对Al_3Zr和Al_3(Zr_(1-x)V_x)、Al_3(Zr_(1-x)Ti_x)和Al_3(Zr_(1-x-y)V_xTi_y)(L1_2)在425°C下析出物的粗化研究的比较证实了三元合金添加剂没有影响。

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