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Fracture toughness of high‐impact polystyrene based on threej‐integral methods

机译:基于三维积分法的高抗冲聚苯乙烯断裂韧性

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AbstractThreeJ‐integral methods and their modified versions have been used to characterize the fracture toughness of high‐impact polystyrene (HIPS) with different thicknesses. TheJcvalues obtained were highest from the E813–87 method, followed by the E813–81 method, then by the hysteresis method. The hysteresis method based on the steep rising of hysteresis energy under constant displacement‐controlled loading inJcdetermination has many advantages over the ASTM E813–81 or the E813–87 method. The requirement of crack growth length measurements is no longer necessary and the controversial issue on the crack blunting line can also be avoided. The E813–87 method resulted in significantly higherJcvalues for polymers, but the modified version of E813–87, by moving the offset line from the original 0.2 to 0.1 mm, resulted in comparableJcvalues. Since crazes as the main failure mechanism for HIPS, well‐defined crack blunting does not expect to occur and theJcobtained by the original E813–81 based on the theoretically predicted blunting line is indeed slightly higher. The modified version of E813–81 by neglecting the blunting line inJcdetermination is believed to be more reasonable for HIPS. The nature of polymers will determine whether the crack tip will be blunted, partially blunted, or not blunted. ASTM E813–81 is appropriate for those polymers with a well‐defined blunted crack tip (such as elastomer‐modified polycarbonate), whereas the modified version of ASTM E813–81 seems better for those polymers with craze as the main failure mechanism (such as HIPS). Experimental results indicated that this hysteresis method is able to inherently adjust the crack blunting effect and therefore can be applied to any type of ductile polym
机译:摘要采用三J积分法及其改进方法表征了不同厚度高抗冲聚苯乙烯(HIPS)的断裂韧性。E813-87 方法获得的 Jc值最高,其次是 E813-81 方法,然后是滞后方法。与ASTM E813-81或E813-87方法相比,基于恒位移控制载荷下滞后能量急剧上升的滞后方法具有许多优点。不再需要测量裂纹扩展长度,也可以避免裂纹钝化线上有争议的问题。E813-87 方法使聚合物的 Jc值显著升高,但 E813-87 的修改版本通过将偏移线从原来的 0.2 mm 移动到 0.1 mm,产生了可比较的 Jc值。由于裂纹是HIPS的主要破坏机制,因此预计不会发生明确的裂纹钝化,而原E813-81基于理论预测的钝化线获得的Jc确实略高。E813-81 的修改版本通过忽略 Jcdetermination 中的钝化线被认为对 HIPS 更合理。聚合物的性质将决定裂纹尖端是否会变钝、部分变钝或不变钝。ASTM E813-81 适用于那些具有明确定义的钝裂纹尖端的聚合物(例如弹性体改性聚碳酸酯),而 ASTM E813-81 的改良版本似乎更适合那些以裂纹为主要失效机制的聚合物(例如 HIPS)。实验结果表明,这种滞后方法能够固有地调节裂纹钝化效应,因此可以应用于任何类型的韧性多晶

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