Semi‐ and fully interpenetrating polymer networks based on polyurethane‐polyacrylate systems. VIII. The influence of the degree of crosslinking of the second formed network on the morphology and properties of polyurethane polymethylacrylate interpenetrating polymer networks

摘要

AbstractA series of polyurethane–polymethylacrylate sequential interpenetrating polymer networks containing 40 by weight of polyurethane were prepared in which the levels of crosslinking in the second formed network—polymethylacrylate—was systematically altered over a wide range. The polymethylacrylate networks and the interpenetrating polymer networks were investigated using dynamic mechanical analysis, sonic velocity measurements, and tensile testing. In addition, the interpenetrating polymer networkds were studied using transmission electron microscopy. The interpenetrating polymer networks showed high values of the Oberst damping factor. It was concluded that tightening the second formed network does not produce the dramatic effects associated with decreasing the average molecular weight between crosslinks of the first formed ne