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The electrical and thermal conductivity of woven pristine and intercalated graphite fiber-polymer composites

机译:编织原始和插层石墨纤维-聚合物复合材料的导电性和导热性

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摘要

A series of woven fabric laminar composite plates and narrow strips were fabricated from a variety of pitch-based pristine and bromine intercalated graphite fibers in an attempt to determine the influence of the weave on the electrical and thermal conduction. It was found generally that these materials can be treated as if they arc homogeneous plates. The rule of mixtures describes the resistivity of the composite fairly well if it is realized that only the component of the fibers normal to the equipotential surface will conduct current. When the composite is narrow with respect to the fiber weave, however, there is a marked angular dependence of the resistance which was well modeled by assuming that the current follows only along the fibers (and not across them in a transverse direction), and that the contact resistance among the fibers in the composite is negligible. The thermal conductivity of composites made from less conductive fibers more closely followed the rule of mixtures than that of the high conductivity fibers, though this is thought to be an artifact of the measurement technique. Electrical and thermal anisotropy could be induced in a particular region of the structure by weaving together high and low conductivity fibers in different directions, though this must be done throughout all of the layers of the structure as interlaminar conduction precludes having only the top layer carry the anisotropy. The anisotropy in the thermal conductivity is considerably less than either that predicted by the rule of mixtures or the electrical resistivity.
机译:以各种沥青基原始和溴插层石墨纤维为原料,制备了一系列机织织物层流复合板和窄条,试图确定织法对导电和导热的影响。人们普遍发现,这些材料可以被视为电弧状的均质板。混合物规则很好地描述了复合材料的电阻率,如果意识到只有垂直于等电位表面的纤维成分才会传导电流。然而,当复合材料相对于纤维编织较窄时,电阻存在明显的角度依赖性,通过假设电流仅沿纤维(而不是横向穿过纤维)很好地建模,并且复合材料中纤维之间的接触电阻可以忽略不计。与高导电性纤维相比,由导电性较低的纤维制成的复合材料的导热性更严格地遵循混合物的规则,尽管这被认为是测量技术的产物。通过在不同方向上将高电导率和低电导率纤维编织在一起,可以在结构的特定区域诱导电各向异性,尽管这必须在结构的所有层中进行,因为层间传导排除了只有顶层携带各向异性。热导率的各向异性远小于混合物规则或电阻率预测的各向异性。

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