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Application of activated carbon in a microwave radiation field to treat trichloroethylene

机译:活性炭在微波辐射场处理三氯乙烯中的应用

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摘要

Desorption and destruction are successfully applied to treat hazardous/toxic organic compounds such as trichloroethylene (TCE), para-xylene, naphthalene, and some gasoline-type of hydrocarbon materials. A process based on low power density microwave (MW) radiation can easily combine these two technologies by only adding granulated activated charcoal (GAC). A fluidized-bed reactor can be used for the treatment of TCE, fluidized with air or argon-containing volatilized organic compounds (VOCs). A MW desorption of the TCE in the reactor is achieved by inducing steam distillation in the GAG. A destruction of the organic compounds in the process is occurred to are between GAC particles while they are exposed to MW radiation. All these organic compounds can be decomposed up to 100. This means that they are non-detectable with GC-MS. In the experiments, GC-MS is used to detect VOCs such as TCE. Here, only hydrogen chloride (HCl) and carbon dioxide (CO2) can be detected as products. It also allows a mass balance for the experimental results, since no other organic compounds can be found in the gas phase analyzed by applying a GC-MS system. (C) 1998 Elsevier Science Ltd. All rights reserved. References: 20
机译:解吸和破坏成功地用于处理危险/有毒的有机化合物,如三氯乙烯(TCE)、对二甲苯、萘和一些汽油型碳氢化合物材料。基于低功率密度微波 (MW) 辐射的工艺只需添加颗粒活性炭 (GAC) 即可轻松结合这两种技术。流化床反应器可用于处理用空气或含氩气的挥发性有机化合物 (VOC) 流态化的 TCE。通过在GAG中诱导蒸汽蒸馏来实现反应器中TCE的MW解吸。当有机化合物暴露于MW辐射时,GAC颗粒之间会发生有机化合物的破坏。所有这些有机化合物的分解率最高可达100%。这意味着它们无法用GC-MS检测。在实验中,GC-MS用于检测TCE等VOC。在这里,只有氯化氢 (HCl) 和二氧化碳 (CO2) 可以作为产物进行检测。它还允许对实验结果进行质量平衡,因为在应用GC-MS系统分析的气相中找不到其他有机化合物。(C) 1998 Elsevier Science Ltd.保留所有权利。[参考文献: 20]

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