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Determination of the photocatalytic activities of titanium dioxides and other white pigments

机译:二氧化钛和其他白色颜料的光催化活性的测定

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AbstractTitanium dioxide, zinc oxide, and other white pigments are widely used in protective coatings and textile applications. An undesirable property of such pigments is their behavior as photo‐oxidation catalysts. As a measure of the activities of various pigments, quantum yields were determined for the photo‐oxidation of isopropyl alcohol to acetone in a system where the pigment was the only absorbing species. An absolute quantum yield of 0.5 was found for reagent‐grade anatase; relative quantum yields were determined for various commercial anatase and rutile titanium dioxides, zinc oxide, barium sulfate, and barium tungstate. A good correlation was found between the photodegradation rates of pigmented polypropylenes, the photodegradation rates of the dyes in pigmented cellulose acetate butyrate, and the activities of the pigments determined by the isopropyl alcohol oxidation m
机译:摘要钛白粉、氧化锌等白色颜料广泛应用于防护涂料和纺织应用。这种颜料的一个不良特性是它们作为光氧化催化剂的行为。作为各种颜料活性的量度,确定了在颜料是唯一吸收物质的系统中将异丙醇光氧化为丙酮的量子产率。试剂级锐钛矿的绝对量子产率为0.5;测定了各种商业锐钛矿和金红石型钛白粉、氧化锌、硫酸钡和钨酸钡的相对量子产率。色素聚丙烯的光降解速率、色素色素乙酸丁酸纤维素中的光降解速率与异丙醇氧化法测定的颜料活性之间存在良好的相关性。

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