AbstractThe solution polymerization of acrylamide initiated by 4,4′‐azobis‐4‐cyanovaleric acid (ACV) at high monomer concentrations in the temperature range 25–50°C has been studied. Molecular weight distributions were measured by gel permeation chromatography and by electron microscopy. Molecular weight measurements show that transfer to monomer plays a dominant role in controlling the molecular weigh
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