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Adsorption of methyl violet from aqueous solution by polyacrylamide as an adsorbent: Isotherm and kinetic studies

机译:聚丙烯酰胺作为吸附剂从水溶液中吸附甲基紫:等温线和动力学研究

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摘要

In this study, polyacrylamide was utilized as a potential adsorbent for the removal of textile dye methyl violet (MV). The optimum conditions for adsorption by using a batch method were evaluated by changing various parameters such as contact time, adsorbent dose, initial pH of the solution and temperature. The adsorption equilibrium was well described by the Langmuir isotherm model with maximum adsorption capacity of 1136 mg g~(-1) of methyl violet on polyacrylamide (PAA). The observed increase in adsorption with increasing temperature suggests that the adsorption of dye on polyacrylamide is endothermic in nature. Methyl violet adsorption followed pseudo-second-order rate kinetics. From kinetic studies, various rates and thermodynamic parameters such as enthalpy, free energy and entropy changes were calculated and these values show that the MV-PAA adsorption process was favored at high temperatures.
机译:本研究将聚丙烯酰胺用作去除纺织染料甲基紫(MV)的潜在吸附剂。通过改变接触时间、吸附剂剂量、溶液初始pH值和温度等各种参数,评估了采用间歇法吸附的最佳条件。Langmuir等温线模型对聚丙烯酰胺(PAA)的最大吸附容量为1136 mg g~(-1)的甲基紫,很好地描述了其吸附平衡。观察到的吸附随着温度的升高而增加,表明染料在聚丙烯酰胺上的吸附本质上是吸热的。甲基紫吸附遵循准二级速率动力学。通过动力学研究,计算了各种速率和热力学参数,如焓、自由能和熵变,这些值表明MV-PAA吸附过程在高温下更受青睐。

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