Zur Kenntnis der Methylchlordisilane

摘要

The IR and Raman spectra of the methylchlorodisilanesItoIVare reported. Among the skeletal vibrations, ν SiSi and ν SiCl(2)i.ph. are strongly coupled; the SiSi-stretching force constant increases regularly from Si2me6to Si2Cl6. In contrast to other disilane mixtures, the system Si2me6/Si2Cl6underwent no AlCl3-catalyzed rearrangemen