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Comparative study of various methods for thermogravimetric analysis of polystyrene degradation

机译:聚苯乙烯降解热重分析方法的比较研究

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AbstractVarious methods of thermogravimetric analysis were compared in case of polystyrene degradation. The reaction order, the activation energy and the preexponential factor were evaluated from common TG curves experimentally obtained. In most cases a 5‐mg sample of polystyrene with 110,000 molecular weight was decomposed at heating rate of 10°C/min. The reaction was found under this experimental condition to be of first order with activation energy of 61.0 kcal/mole, though there were slight differences depending on the analytical methods us
机译:摘要比较了各种热重分析方法在聚苯乙烯降解过程中的应用。从实验得到的常见TG曲线中评估反应顺序、活化能和指数前因子。在大多数情况下,分子量为 110,000 的 5 mg 聚苯乙烯样品以 10°C/min 的加热速率分解。在该实验条件下发现该反应是一级反应,活化能为61.0 kcal/mole,但根据分析方法的不同,存在细微差异。

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