Theoretical studies on the adsorption from non-ideal binary liquid mixtures on heterogeneous surfaces involving difference in molecular sizes of components

摘要

An equation for the phenomenon of competetive adsorption from binary liquid mixtures onto solids has been derived using the kinetic approach. In this equation the difference of the molecular sizes, the non-ideality of both bulk surface phases, and the energetic heterogeneity of the solid surface have been taken into account.