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Spontaneous emission of Eu3(+) ions in a cholesteric liquid crystal

机译:胆甾液晶中Eu3(+)离子的自发发射

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Cholesteric liquid crystals (CLC) possess a characteristic handedness that causes right and left circularly polarized waves to propagate with different group velocities. According to the nature of the used liquid crystal one of the two modes of propagation can experience an almost zero group velocity which yields a high density of modes in the vicinity of the edges of the stop-bands where this mode density becomes null. The other mode is unaffected by the structure and behaves as in free space. These features have a consequence on the spontaneous emission process of an atom introduced as a dopant in such a medium which depends on the mode structure of the surrounding environment. We present here a theoretical description of the spontaneous emission of atoms in a CLC by introducing two different photon reservoirs corresponding to the two different modes of propagation. These elements of theory are shown to be applicable to the case of a Eu (thenoyltrifluoroacetonate)-(TTA)(3) (cholesteryl myristate (M) or pelargonate (P)) complex mixed with a CLC, the selective reflection band of which has been tuned to the mean wavelength of the D-5(0)-->F-7(2) transition of the emission spectrum of the Eu3+ ion. References: 38
机译:胆甾物液晶 (CLC) 具有特有的手性,可导致左右圆偏振波以不同的群速度传播。根据所用液晶的性质,两种传播模式中的一种可以经历几乎为零的群速度,从而在阻带边缘附近产生高密度的模式,此时该模式密度变为零。另一种模式不受结构的影响,其行为与自由空间相同。这些特征对在这种介质中作为掺杂剂引入的原子的自发发射过程有影响,这取决于周围环境的模式结构。我们在这里通过引入对应于两种不同传播模式的两种不同的光子库,对CLC中原子的自发发射进行了理论描述。这些理论要素被证明适用于Eu(噻吩基三氟乙酮)-(TTA)(3)(胆固醇肉豆蔻酸酯(M)或天竺葵酸酯(P))配合物与CLC混合的情况,其选择性反射带已调谐到Eu3+离子发射光谱的D-5(0)-->F-7(2)跃迁的平均波长。[参考文献: 38]

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