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Rubber‐Modified epoxies. IV. Influence of morphology on mechanical properties

机译:橡胶改性环氧树脂。四、形貌对力学性能的影响

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AbstractThe mechanical properties of a system consisting of a bisphenol A diglycidylether (DGEBA) expoxy, cured with a cycloaliphatic diamine (4,4′‐diamino‐3,3 dimethyldicyclohexyl‐methane, 3DCM), in the presence of an epoxy‐terminated butadiene‐acrylonitrile random copolymer (ETBN), was studied as a function of the cure schedule and the initial rubber concentration. Fracture toughness (KIc) and fracture energy (GIc) were increased, while Young's modulus and yield strength decreased slightly with increasing volume fraction of the dispersed phase. We show that there is no significant influence of the precure schedule and of the various observed particle diameters on the mechanical properties for a constant rubber volume fraction. In our case, the main deformation process in the rubber‐modified epoxy networks is shear yielding while cavitation
机译:摘要研究了在环氧封端丁二烯-丙烯腈无规共聚物(ETBN)存在下,用脂环族二胺(4,4′-二氨基-3,3二甲基二环己基-甲烷,3DCM)固化的双酚A二甘油腈(DGEBA)外氧基体系的力学性能,作为固化时间表和初始橡胶浓度的函数。随着分散相体积分数的增加,断裂韧性(KIc)和断裂能(GIc)均有所增加,而杨氏模量和屈服强度略有下降。我们表明,预固化计划和各种观察到的粒径对恒定橡胶体积分数的机械性能没有显着影响。在我们的例子中,橡胶改性环氧网络中的主要变形过程是空化时的剪切屈服

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