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Synthesis of PEDOT nanoparticles and vesicles by dispersion polymerization in alcoholic media

机译:在酒精介质中分散聚合合成PEDOT纳米颗粒和囊泡

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摘要

The synthesis of PEDOT nanoparticles and vesicles by dispersion polymerization in a methanol/water mixture (3/2, v/v) is reported, using either ammonium persulfate or iron(III) p-toluenesulfonate as oxidants and alpha-EDOT-PEO as a reactive stabilizer. The influence of the oxidant as well as the alpha-EDOT-PEO molar mass and concentration on the core-shell particle morphology and conductivity properties have been investigated. PEDOT particles with conductivities up to 1.5 x 10(-2) S . cm(-1) have been obtained in high yield.
机译:报道了使用过硫酸铵或对甲苯磺酸铁(III)作为氧化剂和α-EDOT-PEO作为反应稳定剂,通过在甲醇/水混合物(3/2,v / v)中的分散聚合合成PEDOT纳米颗粒和囊泡。研究了氧化剂以及α-EDOT-PEO摩尔质量和浓度对核壳颗粒形貌和电导率性能的影响。电导率高达 1.5 x 10(-2) S 的 PEDOT 颗粒。cm(-1) 已获得高产率。

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