New Complexes of Copper(II) with a Schiff Base Derived from 2-Phenyl-L, 2, 3-triazole-4-carboxaldehyde and Aniline

摘要

Copper(II) complexes of 2-phenyl-1, 2, 3-triazole-4-carboxalideneaniline (PTCA) have been synthesised and characterised using elemental analysis, conductance and magnetic measurements, IR, electronic and E. S. R. spectral studies, cyclic voltammetry and thermal analyses. The complexes have the general empirical formula Cu(PTCA)2X2 (when X=Cl, Br or acetate group.) or Cu(PTCA)2XX (when X=ClO4). A distorted octahedral structure has been assigned for the complexes.