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Synthesis and characterization of superconducting NbC nanotubes

机译:超导NbC纳米管的合成与表征

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摘要

The discovery of carbon nanotubes in 1991 1 has aroused a great deal of interest in one-dimensional nanomaterials 2,3- Carbon nanotubes have also been used as templates to fabricate other one-dimensional nanomaterials 4. Niobium carbide (NbC) is a very important non-oxide ceramic for its high-melting point (3610 deg C), high hardness, excellent chemical stability, and good wear resistance. NbC also exhibits high conductivity with a normal resistivity of 4.6 mOhm/cm and superconductivity at 12 K 5. Due to these attractive properties, NbC has potential applications in mechanical, chemical, and microelectronic industries 6. NbC was usually prepared by various high temperature reactions 7. Recently, various efforts have been made to synthesize NbC at lower temperatures 8,9. However, there is so far no report about the preparation of NbC nanotubes. Preparing crystalline NbC, especially NbC nanotubes at low temperature still remains a challenge.
机译:1991年碳纳米管的发现[1]引起了人们对一维纳米材料的极大兴趣[2,3]-碳纳米管也被用作制造其他一维纳米材料的模板[4]。碳化铌(NbC)是一种非常重要的非氧化物陶瓷,具有高熔点(3610°C)、高硬度、优异的化学稳定性和良好的耐磨性。NbC还表现出高电导率,正常电阻率为4.6 mOhm/cm,在12 K时具有超导性[5]。由于这些吸引人的特性,NbC在机械、化学和微电子工业中具有潜在的应用[6]。NbC通常通过各种高温反应制备[7]。最近,人们为在较低温度下合成NbC做出了各种努力[8,9]。然而,到目前为止,还没有关于NbC纳米管制备的报道。在低温下制备结晶NbC,特别是NbC纳米管仍然是一个挑战。

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