Determination of Etofenprox in environmental samples by HPLC after anionic surfactant micelle-mediated extraction (coacervation extraction)

摘要

A method is described for determination of residues of the insecticide Etofenprox in environmental samples. Anionic surfactant micelle-mediated extraction (coacervation extraction) was evaluated for isolation of Etofenprox before HPLC. The optimum conditions used for extraction included: 0.09 g sodium dodecanesulfonate (SDoS), 3.1 mL (3.3, for concentrations below 0.04 mg L-1) 12 mol L-1 HCl, 5 min vortex stirring, 5 min centrifugation at 4000 rpm, 2 h equilibration time. The limits of quantification (LOQ) and detection (LOD) were 0.01 and 0.004 mg L-1, respectively, and recoveries obtained from five real samples ranged from 94.33 +/- 2.48 to 100.13 +/- 2.71. The precision of the method was good; relative standard deviations (RSD) were less than 7.