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Fracture in single-layer zirconia (YSZ)-bond coat alloy (NiCoCrAlY) composite coatings under thermal shock

机译:单层氧化锆(YSZ)结合涂层合金(NiCoCrAlY)热冲击作用下的断裂

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摘要

Yttria-stabilized zirconia (YSZ)-NiCoCrAlY bond coat (BC) alloy composites constitute the individual layers of functionally graded thermal barrier coatings (TBCs). Characterizing the fracture response of these composites under thermo-mechanical loads is vital for the design of durable graded TBCs. Accordingly, thermal fracture in plasma sprayed single-layer YSZ-BC alloy composite coatings, subjected to a single high heat flux laser heating-ambient cooling cycle is investigated. Coatings with three different YSZ volume fractions (100 percent, 80 percent and 40 percent YSZ), all having similar thermal resistance were studied. It was found that under similar thermal loads, longer surface cracks as well as horizontal cracks near the coating-BC layer interface resulted in coatings with higher BC alloy (lower YSZ) content. These findings are discussed by considering the effective time-dependent (viscoplastic) behavior and fracture toughness of these composites predicted from micromechanics models. Potential implications of these results on the design of graded TBC systems are briefly discussed.
机译:钇稳定氧化锆 (YSZ)-NiCoCrAlY 粘结涂层 (BC) 合金复合材料构成了功能梯度热障涂层 (TBC) 的各个层。表征这些复合材料在热机械载荷下的断裂响应对于设计耐久级配TBC至关重要。 因此,研究了等离子喷涂单层YSZ-BC合金复合涂层在单个高热通量激光加热-环境冷却循环下的热断裂。研究了具有三种不同YSZ体积分数(100%、80%和40%YSZ)的涂层,它们都具有相似的热阻。结果表明,在相似的热负荷下,较长的表面裂纹以及涂层-BC层界面附近的水平裂纹导致涂层具有较高的BC合金含量(较低的YSZ)。通过考虑从微观力学模型预测的这些复合材料的有效时间依赖性(粘塑性)行为和断裂韧性来讨论这些发现。简要讨论了这些结果对分级TBC系统设计的潜在影响。

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