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The strain dependence of rubber viscoelasticity. Part II. The influence of carbon black

机译:橡胶粘弹性的应变依赖性。第二部分.炭黑的影响

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AbstractElastic and viscous components of the dynamic Young's modulus were measured at strains up to 80 and over a temperature range of −30°C. to +30°C. for natural rubber containing 18 by volume of carbon black. These components were derived from the velocity and attenuation of 1 kcycle/sec. longitudinal waves in stretched filaments. Two types of carbon black were examined, with mean particle diameters of about 0.4 microns (MT black) and 0.04 microns (HAF black). It was possible to represent the strain dependence of the modulus components of the MT‐filled material by the linear relations previously developed for the gum rubber; division by a volume loading factor derived from the Guth‐Simha‐Gold equation gave close agreement with the corresponding values for the gum at the same strain and temperature. The strain dependence of the HAF‐filled rubber was analyzed with reference to the equilibrium modulus‐extension curve. This material showed increases in modulus components much greater than indicated by the volume loading factor and the temperature coefficients of these components were much less than for the gum rubber. The glass‐transition temperature of −65.7°C. for the gum rubber was not significantly affected by the presence of e
机译:摘要动态杨氏模量的弹性和粘性分量是在高达80%的应变和−30°C至+30°C的温度范围内测量的,用于含有18%体积炭黑的天然橡胶。这些分量来自拉伸细丝中 1 kcycle/sec 纵波的速度和衰减。研究了两种类型的炭黑,平均粒径约为0.4微米(MT黑)和0.04微米(HAF黑)。可以通过先前为胶橡胶开发的线性关系来表示 MT 填充材料模量分量的应变依赖性;除以从Guth-Simha-Gold方程得出的体积负荷因子,与相同应变和温度下胶的相应值非常吻合。参考平衡模量延伸曲线分析了HAF填充橡胶的应变依赖性。这种材料的模量成分的增加远大于体积负载因子所指示的,并且这些成分的温度系数远小于胶橡胶。胶橡胶的玻璃化转变温度为−65.7°C,不受e的显著影响

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