Reaction of Methyl Acrylate with N,N-Dimethylethanolamine in the Presence of a Titanium Alkoxide

摘要

The kinetic features were examined for transesterification of methyl acrylate with N,N-dimethyletha-nolamine in the presence of tetra(N, N-dimethylaminoethyl) titanate at different molar ratios of the reactants and at temperatures within 50-80°C, as well as for side reactions of Michael addition at 95-125°C. The major parameters governing the selectivity of the synthesis of N,N-dimethylaminoethyl acrylate were determined.