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Catalyst free synthesis of high-purity carbon nanotubes by thermal plasma jet

机译:热等离子体射流无催化剂合成高纯碳纳米管

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摘要

Carbon nanotubes 1 (CNTs) have generated a great deal of interest due to their unique structure and a wide range of potential applications 2,3. Several methods, such as electric arc discharge, laser ablation and thermal chemical vapor deposition (CVD) through decomposition of hydrocarbons have been successfully developed to produce CNTs 3-6. The arc discharge method can produce high-quality nanotubes and on a relatively large scale. However, it has one fatal drawback for industrial scale production in that it is a discontinuous process and consumes relatively large amounts of energy. Furthermore, the soot contains a lot of by-products such as amorphous carbon and carbon nanoparticles 7, The carbon source is graphite, which is very hard to atomize, because the melting and boiling points are unusually high; about 4100 and 4470 K, respectively. Recently, the thermal plasma jet (TPJ) method has been used to synthesize high-quality CNTs at high temperature by introducing a catalyst source 8,9. This is a continuous process, and the carbon source of hydrocarbons or alcohols is atomized by TPJ at a very high temperature, ~10~4K.
机译:碳纳米管[1](CNTs)因其独特的结构和广泛的潜在应用而引起了人们的极大兴趣[2,3]。已经成功开发了几种方法,如电弧放电、激光烧蚀和通过分解碳氢化合物的热化学气相沉积(CVD)[3-6]。电弧放电方法可以生产高质量的纳米管,并且规模相对较大。然而,对于工业规模生产来说,它有一个致命的缺点,因为它是一个不连续的过程,消耗相对大量的能源。此外,烟灰中含有大量副产物,如无定形碳和碳纳米颗粒[7],碳源是石墨,由于熔点和沸点异常高,很难雾化;分别约为 4100 和 4470 K。最近,热等离子体射流(TPJ)方法已被用于通过引入催化剂源在高温下合成高质量的碳纳米管[8,9]。这是一个连续的过程,碳氢化合物或醇类的碳源在非常高的温度~10~4K下被TPJ雾化。

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