Ultraviolet laser photolysis of chlorine (lgr;=350ndash;360 nm) has been used to produce a microscopic atomic chlorine source. Crystalline silicon has been etched and deep throughhyphen;wafer vias have been fabricated. The etching process has been modeled as a combination of diffusion from the Cl source, and recombination and etching at the silicon surface. Both experimental and theoretical results are given.
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