Isotherm equations for adsorption on heterogeneous microporous solids

摘要

The overall isotherm equations have been derived for adsorption from gaseous and liquid phases on heterogeneous microporous solids by solvingStoeckli's integral equation. In this integral theDublin-Radushkevichequation is used to describe the local adsorption on micropores having identical shape and dimensions. The above integral has been solved for different types of distribution functions characterizing heterogeneity of microporous structure of the solids.