Development and Laboratory Investigations of a Denuder Sampling System for the Determination of Heavy Metal Species in Flue Gases at Elevated Temperatures

摘要

A denuder sampling system was developed to measure volatile metals at elevated temperatures. By using the denuder technique it is possible to avoid condensation and adsorption losses in the sampling line. To investigate the behavior of heavy metal species under different physical and chemical conditions, a laboratory scale quartz stack was built. Metal aerosol generators based on evaporation, diffusion and condensation are described. The diameter of the generated particles varied between 0.05#x2013;0.3 #x3BC;m. The day to day reproducibility of the generation varied between 0.6-5.0 for chromium and 2.8#x2013;4.0 for cadmium (95 stat. significance).