Kinetics of 1‐hexene polymerization

摘要

AbstractKinetics of 1‐hexene polymerization was studied by following the amount of unreacted monomer using gas chromatography. The Ziegler‐Natta catalyst system used was comprised of TiCl4‐AlEt3with Al: Ti ratio of 0.85. The sampling and monomer analysis techniques developed can be applied to study the kinetics of higher α‐olefins polymerizations, in general. Also, with minor modifications in this technique, a precise profile of molecular weight can be obtained during polyme