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首页> 外文期刊>European journal of wood and wood products >Determining the curing parameters of furfuryl alcohol for wood modification by nanoindentation
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Determining the curing parameters of furfuryl alcohol for wood modification by nanoindentation

机译:纳米压痕法测定糠醇对木材改性的固化参数

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Wood furfurylation is a very promising modification process, which can greatly improve several important properties of wood simultaneously. The polymerization degree of furfuryl alcohol (FA) in wood significantly influences the performances of modified wood. However, it is normally time-consuming and expensive to determine the curing parameters of a new FA solution formula for a target wood species, as the process requires lots of lab-scale experiments. To address this challenge, nanoindentation was used to determine the hardness and elastic modulus of FA resin which are cured with different catalyst content, curing time and curing temperature, assuming that these mechanical properties should closely relate to the polymerization degree of cured FA (resin). Single-factor experiments were designed to obtain preliminary curing parameters. Three key curing parameters were selected, namely the catalyst content of maleic anhydride (1.5, 3, 5 ), curing time (2, 3, 4, 5, 6 h) and curing temperature (95, 105, 115, 125 A degrees C). The proposed set of curing parameters based on the nanoindentation results are 3 maleic anhydride, 3 h curing time and 105 A degrees C curing temperature. This set of parameters was slightly modified and then used as the starting process parameters for Masson pine modification, which resulted in greatly improved wood properties. Therefore, the method proposed in this study offers an effective and time-saving means of developing new processes of wood furfurylation.
机译:木材糠酸化是一种非常有前途的改性工艺,可以同时大大改善木材的几种重要性能。糠醇(FA)在木材中的聚合度对改性木材的性能有显著影响。然而,确定目标树种的新FA溶液配方的固化参数通常既耗时又昂贵,因为该过程需要大量的实验室规模实验。为了应对这一挑战,采用纳米压痕法测定了不同催化剂含量、固化时间和固化温度固化的FA树脂的硬度和弹性模量,假设这些力学性能与固化FA(树脂)的聚合度密切相关。设计单因素实验以获得初步固化参数。选取了马来酸酐催化剂含量(1.5、3、5 %)、固化时间(2、3、4、5、6 h)和固化温度(95、105、115、125 A°C)3个关键固化参数。基于纳米压痕结果提出的固化参数集为3%马来酸酐,固化时间为3 h,固化温度为105 A°C。这组参数稍作修改,然后作为马尾松改性的起始工艺参数,大大改善了木材性能。因此,本研究提出的方法为开发木材糠酸化新工艺提供了一种有效且省时的方法。

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