Strong mechanoluminescence induced by elastic deformation of rare-earth-doped strontium aluminate phosphors

摘要

When rare-earth-doped strontium aluminate phosphor mixed in an epoxy resin, is deformed elastically by applying a uniaxial pressure, then initially the mechanoluminescence (ML) intensity increases with time, attains a peak value I-m at a particular time t(m), and later on it decreases with time. After t(m), initially, the ML intensity decreases exponentially at a fast rate and then it decreases exponentially at a slow rate. The ML appears after a threshold pressure and then, initially at low pressure, the peak intensity Im of ML increases linearly with the magnitude of applied pressure, and for high pressure, I-m increases exponentially with the magnitude of applied pressure. The value of I-m increases linearly with the density of filled hole traps. The ML emission also takes place during the release of applied pressure. There should be a significant effect of temperature on the ML intensity of rare-earth-doped strontium aluminate phosphors. The ML intensity of rare-earth-doped strontium aluminates decreases with successive number of the applications of pressure and the diminished ML intensity can be recovered with the exposure of the samples to UV-radiation. The ML spectra of rare-earth-doped strontium aluminate phosphors are similar to their photoluminescence spectra. As only the piezoelectric-phase of the strontium aluminate phosphors exhibit ML during their elastic deformation, the ML emission can be attributed to the piezoelectrification of the crystals. Considering that the piezoelectric field causes decrease in the trap-depth of the hole traps and, therefore, the holes transferred from traps to the valence band recombine with (Eu1+)* ions, whereby the Eu2+ ions are excited, expressions are derived for different parameters of ML, which are able to satisfactorily explain the experimental results. It is shown that the lifetimes of holes in the shallow traps in stressed and unstressed materials, and the threshold pressure P-t for the ML emission, and other parameters of the ML, can be determined from the ML measurements. Finally, the criteria for tailoring strong elasico-mechanoluminescent materials are explored.