Laboratory and field studies on a new sensor for dissolved N2O

摘要

Nitrous oxide (N2O) is a strong greenhouse gas, whose atmospheric concentration has been continuously increasing for more than 200 years. One major source is wastewater treatment plants (WWTPs), where N2O emissions should either be minimized or pushed to levels where exploitation in biogas combustion engines becomes efficient. Both these strategies require online control of the N2O concentrations in the liquid as well as in the gas phase. For this purpose, we propose a system for membrane extraction of the gas from the liquid phase, which then allows for a subsequent gas-phase analysis, which we perform by photoacoustic spectroscopy. We compare different theoretical calculations of the extraction efficiency, based either on a straightforward mathematical model or on a finite element simulation. The comparison of results with measurements produced on a well-defined model system shows good accordance. Based on the outcome, a field probe was developed and tested on a WWTP, yielding results comparable to the one achieved by GC reference analysis.