Line intensities of acetylene in the 3-mu m region: New measurements of weak hot bands and global fitting

摘要

About 170 line intensities of 14 weak parallel hot bands of acetylene have been measured in the 3-mu m region. Absolute values of line intensities are obtained with a mean uncertainty of 10, except for a few lines of 3 very weak bands (Uncertainty Lip to 20). Vibrational transition dipole moment and Herman-Wallis coefficients have been determined for each measured band. These measured line intensities together with previously published ones (JQSRT 2005;92:239-60) have been treated simultaneously within the framework of the effective operators approach. Using only 6 effective dipole moment parameters, it was possible to reproduce the 591 measured line intensities of the 20 bands with a root mean square of the residuals equal to 4.2. (c) 2005 Elsevier Ltd. All rights reserved.