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Adsorption characteristics of polyacrylamide and sulfonate‐containing polyacrylamide copolymers on sodium kaolinite

机译:聚丙烯酰胺和含磺酸盐的聚丙烯酰胺共聚物在高岭石钠上的吸附特性

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摘要

AbstractPolyacrylamide and its copolymer containing 6.8 mole 2‐acrylamido‐2‐methylpropane sulfonic acid were prepared by an irradiation‐initiated precipitation polymerization technique. The polymer was characterized by intrinsic viscosity under conditions similar to those used during adsorption measurements. Hydrolytic degradation of the polyacrylamide was found to be negligible under conditions used. The adsorption substrate, sodium kaolinite, was prepared by extensive ion exchange treatment. Equilibrium adsorption of the polymers on the sodium kaolinite was made as a function of polymer concentration, solution pH, ionic strength, and temp
机译:摘要 采用辐照引发沉淀聚合技术制备了含6.8摩尔%2-丙烯酰胺基-2-甲基丙烷磺酸的聚丙烯酰胺及其共聚物。该聚合物的特征是,在与吸附测量期间使用的条件相似的条件下具有特性粘度。发现聚丙烯酰胺的水解降解在使用条件下可以忽略不计。通过广泛的离子交换处理制备了吸附底物高岭石钠。聚合物在高岭石钠上的平衡吸附是聚合物浓度、溶液pH值、离子强度和温度的函数

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