First steps towards alternating copolymers from a functionalized 1.1.1propellane and dendronized acrylates

摘要

The synthesis of some alternating copolymers from a tert-butyl(dimethyl)silyl protected hydroxymethyl substituted 1.1.1propellane and acrylates carrying Frechet-type dendrons of the first and second generation is described. A copolymer with a second generation dendron at every repeat unit was obtained with (M) over bar(w) = 43 700 as determined via gel permeation chromatography. References: 18